N-(4-Methylphenyl)benzamide
نویسندگان
چکیده
The structure of the title compound, C(14)H(13)NO, resembles those of N-(2-chloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(3,4-dichloro-phen-yl)benzamide and 2-chloro-N-(2-chloro-phen-yl)benzamide with similar bond parameters. The benzene and methylphenyl rings have a dihedral angle of 63.41 (5)°, while the amide group makes a dihedral angle of 20.5 (1)° with the benzene ring. The mol-ecules are linked into chains in the b-axis direction by N-H⋯O hydrogen bonds.
منابع مشابه
4-Chloro-N-(3-methylphenyl)benzamide
In the title compound, C(14)H(12)ClNO, the meta-methyl substituent in the aniline ring is positioned anti to the N-H bond. The dihedral angle between the rings is 12.4 (1)°. The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds, which link the mol-ecules into C(4) chains running along the c-axis direction.
متن کامل4-Chloro-2-hydroxy-N-(4-methylphenyl)benzamide
In the title compound, C(14)H(12)ClNO(2), the dihedral angle between the aromatic rings is 14.87 (11)° and an intra-molecular N-H⋯O hydrogen bond generates an S(6) ring. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, generating C(6) chains propagating along the c-axis direction.
متن کاملN-(4-Methylphenyl)-N-{[(2-nitrophenyl)acetyl]oxy}benzamide
In the title mol-ecule, C(22)H(18)N(2)O(5), the nitro-substituted benzene ring makes dihedral angles of 71.56 (1)° with the benzoyl ring and 16.28 (1)° with the methyl-substituted benzene ring. The crystal structure features C-H⋯O inter-actions, which generate chains.
متن کامل2,6-Dichloro-N-(4-methylphenyl)benzamide
In the title compound, C(14)H(11)Cl(2)NO, the two benzene rings are non-coplanar [dihedral angle = 60.9 (3)°]. In the crystal, an amide N-H⋯O hydrogen bond links the mol-ecules into chains which extend along (001).
متن کامل2-Chloro-N-(4-methylphenyl)benzamide
In the title compound, C(14)H(12)ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond. The benzoyl and aniline benzene rings are tilted relative to each other by 82.8 (1)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into infinite chains running along the c-axis direction.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007